A colourless crystalline salt, on being heated, gives a colourless gas with a pungent smell. On bein — Qualitative and Quantitative Analysis Chemistry Question
Question
A colourless crystalline salt, on being heated, gives a colourless gas with a pungent smell. On being passed through an AgNO3 solution, this gas forms a white precipitate insoluble in HNO3 but readily soluble in an NH3 solution. Which of the following reaction can lead to the above observation ?
Answer: A
💡 Solution & Explanation
MgCl2 undergoes partial hydrolysis on heating to release HCl gas (pungent smell). HCl reacts with AgNO3 to form AgCl (white ppt), which is soluble in NH3 forming [Ag(NH3)2]+.
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