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These are physical properties of an element (a) Sublimation enthalpy (b) Ionisation enthalpy (c) Hydp Block Elements Chemistry Question

Question

These are physical properties of an element (a) Sublimation enthalpy (b) Ionisation enthalpy (c) Hydration enthalpy (d) Electron gain enthalpy The total number of above properties that affect the reduction potential is ________ (Integer answer)

Answer: 3.00

💡 Solution & Explanation

**Step 1: Recall the Born-Landé equation for reduction potential** The reduction potential (E°) of an element depends on the thermodynamic cycle involving ionization and hydration of ions. The key relationship is: E° ∝ (Ionization Enthalpy + Hydration Enthalpy) / (other factors) **Step 2: Analyze Ionization Enthalpy** Ionization enthalpy (IE) is required to remove electrons from the neutral atom. Higher IE means the element is harder to oxidize, affecting reduction potential directly. ✓ Affects E° **Step 3: Analyze Hydration Enthalpy** Hydration enthalpy (ΔH_hyd) is released when gaseous ions are hydrated in solution. This energy release stabilizes the ion, making reduction more favorable. ✓ Affects E° **Step 4: Analyze Sublimation Enthalpy** Sublimation enthalpy converts solid metal to gaseous atoms. This is part of the thermodynamic cycle for reduction potential. ✓ Affects E° **Step 5: Analyze Electron Gain Enthalpy** Electron gain enthalpy applies to non-metals gaining electrons (reduction). For metal reduction potentials (M → M^n+), this doesn't apply. ✗ Does not affect E° **Step 6: Count the properties** Properties affecting reduction potential: - Sublimation enthalpy (a) ✓ - Ionization enthalpy (b) ✓ - Hydration enthalpy (c) ✓ - Electron gain enthalpy (d) ✗ Therefore, the answer is 3.00.

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