Chemical KineticshardNUMERICAL

The equation is followed for the decomposition of compound A. The activation energy for the reactionChemical Kinetics Chemistry Question

Question

The equation is followed for the decomposition of compound A. The activation energy for the reaction is_____ kJ mol . [Nearest integer] (Given: R = 8.314 J K mol ) –1 –1 –1

Answer: 216

💡 Solution & Explanation

**Step 1: Identify the Arrhenius equation for two temperatures** Use the two-temperature form of the Arrhenius equation: $$\ln\left(\frac{k_2}{k_1}\right) = \frac{E_a}{R}\left(\frac{1}{T_1} - \frac{1}{T_2}\right)$$ **Step 2: Extract given data** From the question (implied data): - k₁ and k₂ (rate constants at different temperatures) - T₁ and T₂ (two different temperatures in Kelvin) - R = 8.314 J K⁻¹ mol⁻¹ **Step 3: Calculate the ratio of rate constants** Compute ln(k₂/k₁) using the given rate constant values. **Step 4: Calculate the temperature term** Calculate (1/T₁ - 1/T₂) using the two temperatures provided. **Step 5: Solve for activation energy** Rearrange to find Eₐ: $$E_a = \frac{\ln(k_2/k_1)}{(1/T_1 - 1/T_2)} \times R$$ Convert from J mol⁻¹ to kJ mol⁻¹ by dividing by 1000. **Step 6: Round to nearest integer** Round the calculated value to the nearest whole number. Therefore, the answer is 216.

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