Coordination CompoundsmediumNUMERICAL

Consider the following compounds with their regular geometries.<br>A: Square planar<br>B: Trigonal bCoordination Compounds Chemistry Question

Question

Consider the following compounds with their regular geometries.<br>A: Square planar<br>B: Trigonal bipyramidal<br>C: Square pyramidal<br>D: Octahedral<br>E: Pentagonal bipyramidal<br>Calculate value of $(x+y-z)^2$, where x is total number of axial d-orbitals having zero nodal plane, y and z are total no. of non-axial and axial d-orbitals respectively each one having two nodal planes used in hybridization of central atoms of compounds A to E.

Answer: **ANSWER: 0**<BR>SOLUTION: THE HYBRIDIZATIONS ARE A ($DSP^2$, USING $D_{X^2-Y^2}$), B ($SP^3D$, USING $D_{Z^2}$), C ($SP^3D$, USING $D_{X^2-Y^2}$), D ($SP^3D^2$, USING $D_{X^2-Y^2}, D_{Z^2}$), E ($SP^3D^3$, USING $D_{X^2-Y^2}, D_{XY}$). BASED ON THE NUMBER OF NODAL PLANES: $X = D_{Z^2} = 3$, $Y = D_{XY} = 1$, $Z = D_{X^2-Y^2} = 4$. THEREFORE, $(X+Y-Z)^2 = (3+1-4)^2 = 0$.
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