TheChemSolver/Tools/Hydrogen Emission Spectrum

Hydrogen Emission Spectrum — Click Energy Levels to See Photon Wavelength & Color

Click initial and final electron energy levels (n=1 through n=6) to calculate photon wavelength, frequency, and energy for any hydrogen transition.

Unit 1IChO15-day free trial
728×90 Leaderboard
Loading tools…
300×250 Below Tool
320×50 Mobile Anchor

Topics Covered

  • Rydberg formula: 1/λ = R∞(1/n₁² − 1/n₂²)
  • Lyman series (UV): n→1 transitions
  • Balmer series (visible): n→2 transitions
  • Paschen series (IR): n→3 transitions
  • Brackett series (IR): n→4 transitions
  • Photon energy E = hν = hc/λ

How to Use

  1. 1Click a starting energy level (n=2 through 6)
  2. 2Click a final energy level (lower n)
  3. 3Read wavelength in nm, identify the spectral series, and see the visible color band

Curriculum Alignment

AP Chemistry
Unit 1: Atomic Structure and Properties
IChO Syllabus
Included in IChO preparatory topics
Access
Free · No time limit

Hydrogen Emission Spectrum — In Depth

Clicking two energy levels and instantly seeing the resulting photon's exact wavelength and color turns the Rydberg formula from an equation to memorize into a relationship you can verify directly — core AP Chemistry Unit 1 content built entirely from the hydrogen atom's quantized energy levels.

Every electron transition in hydrogen, from any initial level ni down to any final level nf, releases a photon whose wavelength is given exactly by the Rydberg formula: 1/λ = R∞(1/nf² - 1/ni²), with R∞ = 1.097 × 10⁷ m⁻¹. Because hydrogen's energy levels follow En = -13.6 eV/n², larger transitions (bigger gap between ni and nf) release higher-energy, shorter-wavelength photons, while transitions between adjacent, high-n levels release lower-energy, longer-wavelength photons.

The four series are distinguished entirely by their final level: the Lyman series (nf = 1) has the largest possible energy gaps and falls entirely in the ultraviolet, invisible to the human eye. The Balmer series (nf = 2) is uniquely important because it's the only series with lines in the visible spectrum — these are the classic red, cyan, blue, and violet hydrogen emission lines visible directly in a spectroscope, historically the first spectral lines ever measured with precision. The Paschen series (nf = 3) and Brackett series (nf = 4) both fall in the infrared, invisible but detectable with appropriate instruments.

Because every transition within a series shares the same final level, series members converge as ni increases — the energy gap between consecutive transitions shrinks, and the series approaches (but never quite reaches) a series limit corresponding to complete ionization from that final level.

Photon energy, frequency, and wavelength are three ways of describing the same quantity: E = hν = hc/λ, so any transition's photon can be characterized in whichever unit a specific problem asks for, all derived from the same underlying energy-level difference.

This tool lets you click any initial and final energy level from n=1 through n=6, instantly calculates the resulting photon's wavelength, frequency, and energy, and identifies which series and spectral region it belongs to.

728×90 Below Article