SafeScale: worked examples on published kinetics

What multi-rate DSC gives a plant (onset, Ea, TD24), shown on curves simulated from published kinetics.

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di-tert-butyl-peroxide

Di-tert-butyl peroxide (DTBP): DSC onset 151 C, Ea 171 kJ/mol, TD24 about 95 C (simulated from published kinetics)

SafeScale analysis of DSC thermograms simulated at 2, 5 and 10 K/min from published kinetics (Ea 170.3 kJ/mol, log A 17.3, dH 1180 J/g; Iwata Y., 2013, Thermal decomposition behavior of di-tert-butyl peroxide measured with differential adiabatic calorimeter, Chemical Engineering Transactions, 31, 835-840, DOI 10.3303/CET1331140). Simulated from published kinetics, not a measurement. Illustrates what the engine derives from multi-rate DSC; it is not a safety basis for any process. TD24/TD8 use a zero-order Semenov estimate with Cp 2.0 J/g/K.

Frequently asked

Are these measurements?

No. The DSC curves are simulated from published decomposition kinetics, cited on each sample, and analysed by the SafeScale engine. They illustrate the method and are not a safety basis for any process.