Answer the following questions about the solubility of AgCl(s). The value of K_sp for AgCl(s) is 1.8 — Equilibrium Chemistry Question
Problem Context
Answer the following questions about the solubility of AgCl(s). The value of K_sp for AgCl(s) is 1.8 × 10^-10.
Model Answer
K_sp = [Ag+][Cl-]
Let x = [Ag+] = [Cl-]
Then 1.8 × 10^-10 = (x)(x) ⇒ x = √(1.8 × 10^-10)
x = [Ag+] = 1.3 × 10^-5 M
1 point is earned for the correct K_sp expression and indication that the two ions have equal concentrations.
1 point is earned for correct calculation of the value of [Ag+].
Model Answer
1.8 × 10^-10 = [Ag+] × (0.54) ⇒ [Ag+] = 3.3 × 10^-10 M
1 point is earned for the correct answer with supporting work. || An increased [Cl-] will decrease the solubility of AgCl(s) since the K_sp is a product of the [Ag+] and [Cl-]. (This is an example of the common ion effect.)
1 point is earned for a correct explanation.