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KineticsFRQ

2 H2O2(aq) → 2 H2O(l) + O2(g) 2. Hydrogen peroxide, H2O2, decomposes according to the equation aboveKinetics Chemistry Question

Problem Context

2 H2O2(aq) → 2 H2O(l) + O2(g)

  1. Hydrogen peroxide, H2O2, decomposes according to the equation above. This reaction is thermodynamically favorable at room temperature.
a.2 pts

Model Answer

1 point is earned for correctly representing products as H2O and O2 molecules.
1 point is earned for atom balance.

b.2 pts

Model Answer

(i) This reaction is exothermic because the products have lower potential energy than the reactants. Thus, the system has lost potential energy, releasing heat.
1 point is earned for indication that the reaction is exothermic, with a valid justification.

(ii) The curve for the catalyzed reaction has the reactants and products at the same energy levels as the original curve, and a lower activation energy than the original curve.
1 point is earned for a correct curve.

c.2 pts

Model Answer

(i) mass O2 = 43.19 g − 42.58 g = 0.61 g
moles O2 = 0.61 g O2 × (1 mol O2 / 32.00 g) = 0.019 mol O2
1 point is earned for the correct answer.

(ii) mass H2O2 = 0.019 mol O2 × (2 mol H2O2 / 1 mol O2) × (34.02 g H2O2 / 1 mol H2O2) = 1.3 g H2O2
1 point is earned for the correct answer.

d.1 pt

Model Answer

Less than.
The decrease in mass becomes smaller over every subsequent 10-second interval. This decreasing trend would continue in the second minute.
1 point is earned for the correct choice with a valid explanation.

e.1 pt

Model Answer

Disagree.
If the reaction were zeroth-order, the rate of mass loss (which corresponds to the rate of reaction) would be constant until the reactant was consumed. However, the data show that the rate of mass loss from beaker 2 is not constant.
1 point is earned for disagreement and a valid justification.

f.1 pt

Model Answer

Agree.
The calculated amount of O2 produced is based on the change in mass, and in this case some of the change in mass is due to loss of solution rather than production of O2.
1 point is earned for agreement and a valid justification.

g.1 pt

Model Answer

(NH4)2S2O8 + 2 H2O → H2O2 + 2 NH4HSO4
OR
(NH4)2S2O8 + 2 H2O → H2O2 + 2 NH4+ + 2 HSO4-
OR
S2O8 2− + 2 H2O → H2O2 + 2 HSO4−
1 point is earned for a correct balanced equation.

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