BondingFRQ

[VISUAL] Some binary compounds that form between fluorine and various nonmetals are listed in the ta โ€” Bonding Chemistry Question

Problem Context

[VISUAL]

Some binary compounds that form between fluorine and various nonmetals are listed in the table above. A student examines the data in the table and poses the following hypothesis: the number of F atoms that will bond to a nonmetal is always equal to 8 minus the number of valence electrons in the nonmetal atom.

a.1 pt

Model Answer

ClF

1 point is earned for the correct formula.

b.1 pt

Model Answer

1 point is earned for a central Cl atom surrounded by three bonding pairs with F atoms and two nonbonding (lone) pairs of electrons. F atoms must have three nonbonding pairs each. Electron pairs can be depicted as dots or line segments.

c.1 pt

Model Answer

The molecule is T-shaped because a T-shaped structure is asymmetric with dipoles that do not cancel out, but produce a net dipole (i.e., a polar molecule).
OR
because, if the molecule had a trigonal planar structure, the molecule would be symmetric with dipoles that cancel out and produce a net dipole of zero (i.e., a nonpolar molecule), which is not consistent with the observation that the ClF3 molecule does have a dipole moment.

1 point is earned for indicating that the molecule is T-shaped with an acceptable explanation.

d.1 pt

Model Answer

An acceptable hypothesis (descriptive or formulaic) must include the following ideas:
1. Atomic Structure: e.g., odd number of F atoms
2. Periodicity: e.g., as the atomic number of the central halogen atom increases, the number of F atoms increases.

1 point is earned for an acceptably modified hypothesis that addresses both atomic structure and periodicity.

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