[VISUAL] 9. A mixture of CO(g) and O2(g) is placed in a container, as shown above. A reaction occurs — Stoichiometry Chemistry Question
Question
[VISUAL]
- A mixture of CO(g) and O2(g) is placed in a container, as shown above. A reaction occurs, forming CO2(g). Which of the following best represents the contents of the box after the reaction has proceeded as completely as possible?
Box A
Box B
Box C
Box D
💡 Solution & Explanation
STEPS:
1. Write and balance the chemical equation for the reaction:
Carbon monoxide () reacts with oxygen gas () to produce carbon dioxide (). The balanced chemical equation is:
This stoichiometry tells us that 2 molecules of react with exactly 1 molecule of to produce 2 molecules of .
2. Count the initial reactant molecules in the starting container:
Using the key provided (where gray circles represent and white circles represent ):
* molecules (one gray circle bonded to one white circle): Count them systematically to find there are exactly 6 molecules.
* molecules (two bonded white circles): Count them systematically to find there are exactly 4 molecules.
3. Identify the limiting reactant:
Determine how much is needed to react completely with all 6 molecules of :
Because we have 4 molecules of initially and only need 3:
* is the limiting reactant (it will be completely consumed).
* is the excess reactant.
4. Calculate the contents of the container after the reaction goes to completion:
* remaining: Since it is the limiting reactant, remain.
* produced: Since and have a stoichiometric ratio (), completely consuming 6 molecules of produces exactly 6 molecules of (each represented by one central gray circle bonded to two white circles).
* remaining: Out of the initial 4 molecules, 3 are consumed, leaving:
5. Select the corresponding box:
The final container must contain exactly 6 molecules and 1 unreacted molecule. Looking at the choices, Box B matches this composition perfectly, making Option B the correct answer.
*
WHY_OTHERS_WRONG:
- Option A is incorrect (Box A): This box contains 6 molecules but 0 molecules. This representation violates the law of conservation of mass because the two oxygen atoms belonging to the excess, unreacted molecule have completely vanished from the system.
- Option C is incorrect (Box C): This box represents the starting system with no reaction having occurred (it still contains 6 molecules and 4 molecules). This contradicts the prompt, which states that a reaction occurs and proceeds as completely as possible.
- Option D is incorrect (Box D): This box shows 6 molecules along with 4 molecules. For this composition to exist, the final system would need to contain 14 oxygen atoms and 6 carbon atoms, which is far more than the initial starting atoms.