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Atomic StructureMCQ

Which of the following statements about atoms is NOT correct?Atomic Structure Chemistry Question

Question

Which of the following statements about atoms is NOT correct?

A.

Atoms are electrically neutral because they have the same number of protons and electrons.

B.

All atoms of a given element must have the same number of protons, neutrons, and electrons.

✓ Correct
C.

Most of the volume of an atom contains only electrons.

D.

The nucleus is positively charged.

E.

Almost all of the mass of an atom is in the nucleus.

💡 Solution & Explanation

STEPS:

  1. Analyze the Definition of an Element: The identity of a specific chemical element is determined solely by its atomic number, which is the number of protons in the nucleus.
  2. Evaluate the Role of Neutrons: Atoms of the same element can have different numbers of neutrons; these variations are known as isotopes. For example, Carbon-12 and Carbon-14 both have 6 protons but different numbers of neutrons.
  3. Evaluate the Role of Electrons: Atoms can gain or lose electrons to become ions without changing their identity as a specific element.
  4. Identify the False Statement: Because an element can exist as different isotopes (varying neutrons) or ions (varying electrons), it is incorrect to state that all atoms of an element *must* have the same number of neutrons and electrons.
  5. Conclusion: Therefore, statement B is the only incorrect statement among the choices.

WHY_OTHERS_WRONG:

  • A: This is a correct statement; in a neutral atom, the positive charge of the protons is exactly balanced by the negative charge of an equal number of electrons.
  • C: This is correct; according to modern atomic theory, the nucleus is incredibly small, and the vast majority of an atom's volume is the "empty space" occupied by the electron cloud.
  • D: This is correct; the nucleus contains protons, which are positively charged, and neutrons, which are neutral, resulting in a net positive charge.
  • E: This is correct; protons and neutrons each have a mass of approximately 1 amu, while electrons have a negligible mass (about 1/1800th of a proton), meaning the nucleus contains virtually all the mass.
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