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Acids and BasesMCQ

NH3(aq) + HCl(aq) → NH4+(aq) + Cl-(aq) The Brønsted-Lowry bases in the reaction represented above arAcids and Bases Chemistry Question

Question

NH3(aq) + HCl(aq) → NH4+(aq) + Cl-(aq)

The Brønsted-Lowry bases in the reaction represented above are

A.

NH3(aq) and NH4+(aq)

B.

NH3(aq) and Cl-(aq)

✓ Correct
C.

NH3(aq) and HCl(aq)

D.

HCl(aq) and NH4+(aq)

E.

HCl(aq) and Cl-(aq)

💡 Solution & Explanation

STEPS:

1. Define the Brønsted-Lowry Concept: Recall that according to the Brønsted-Lowry theory, an acid is a proton (H+H^+) donor and a base is a proton (H+H^+) acceptor.
2. Analyze the Forward Reaction: Look at the reactants and determine which species is accepting a proton.
* NH3(aq)NH_3(aq) becomes NH4+(aq)NH_4^+(aq). To do this, it must accept a proton (H+H^+) from HClHCl. Therefore, NH3NH_3 is a Brønsted-Lowry base.
3. Identify the Acid and its Conjugate:
* HCl(aq)HCl(aq) becomes Cl(aq)Cl^-(aq) by donating a proton to NH3NH_3. This makes HClHCl the Brønsted-Lowry acid.
* The species that remains after an acid has donated its proton is called the conjugate base. In this reaction, ClCl^- is the conjugate base of HClHCl.
4. Analyze the Reverse Reaction: Consider what would happen if the reaction proceeded in the opposite direction.
* To reform the reactants, Cl(aq)Cl^-(aq) would have to accept a proton from NH4+(aq)NH_4^+(aq) to become HClHCl. Since ClCl^- acts as a proton acceptor in the reverse process, it is also classified as a Brønsted-Lowry base.
5. Conclusion: The two species in this equilibrium system that act as proton acceptors (bases) are NH3(aq)NH_3(aq) and Cl(aq)Cl^-(aq), which corresponds to option B.

WHY_OTHERS_WRONG:

  • NH4+(aq)NH_4^+(aq) (Found in A and D): This is the conjugate acid of NH3NH_3. In the reverse reaction, it would donate a proton to ClCl^- to reform NH3NH_3; therefore, it is an acid, not a base.
  • HCl(aq)HCl(aq) (Found in C, D, and E): HClHCl is a strong acid that dissociates to donate a proton to the base (NH3NH_3). By definition, a proton donor cannot be a Brønsted-Lowry base in the same reaction.
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