Oxygen is acting as an oxidizing agent in all of the following reactions EXCEPT — Electrochemistry Chemistry Question
Question
Oxygen is acting as an oxidizing agent in all of the following reactions EXCEPT
A.
2 C(s) + O2(g) → 2 CO(g)
B.
S(s) + O2(g) → SO2(g)
C.✓ Correct
2 F2(g) + O2(g) → 2 OF2(g)
D.
2 Na(s) + O2(g) → Na2O2(s)
E.
2 Mg(s) + O2(g) → 2 MgO(s)
💡 Solution & Explanation
STEPS:
- Define Oxidizing Agent: An oxidizing agent is a substance that causes another species to be oxidized by accepting electrons. In this process, the oxidizing agent itself is reduced, meaning its oxidation number decreases.
- Identify Initial Oxidation States: In all the provided reactions, oxygen starts in its elemental form as . The oxidation number of any element in its free, uncombined state is 0.
- Evaluate the Role of Electronegativity: Oxygen is the second most electronegative element. In most reactions with other elements, oxygen will attract electrons and take on a negative oxidation state (usually -2), which makes it a very common oxidizing agent.
- Identify the Exception (Fluorine): The only element on the periodic table with a higher electronegativity than oxygen is Fluorine. When these two elements react, Fluorine will "win" the electrons.
- Analyze Choice C (): In the compound oxygen difluoride (), Fluorine must take its standard oxidation state of -1. To balance the two Fluorine atoms and maintain a neutral molecule, the oxygen atom must have an oxidation number of +2.
- Determine the Electron Transfer in C: Because oxygen's oxidation number increases from 0 (in ) to +2 (in ), it has lost electrons and has been oxidized.
- Conclusion: Since oxygen is oxidized in reaction C, it is acting as a reducing agent in that specific case, while Fluorine acts as the oxidizing agent.
WHY_OTHERS_WRONG:
- A, B, D, and E: In these reactions, oxygen is combined with elements that are less electronegative than itself ( and ). In the resulting products ( and ), oxygen takes on a negative oxidation state (-2 or -1). Because oxygen's oxidation number decreases from 0 to a negative value in all these cases, it is being reduced and is successfully acting as an oxidizing agent.
💬
Still have doubts about this question?
Practice more questions like this, completely free.