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Which of the following is the best piece of laboratory glassware for preparing 500.0 mL of an aqueouSolutions Chemistry Question

Question

Which of the following is the best piece of laboratory glassware for preparing 500.0 mL of an aqueous solution of a solid?

A.

Volumetric flask

✓ Correct
B.

Erlenmeyer flask

C.

Test tube

D.

Graduated beaker

E.

Graduated cylinder

💡 Solution & Explanation

STEPS:

  1. Identify the Experimental Goal: The task is to prepare a specific, precise volume (500.0 mL) of an aqueous solution. The decimal point in "500.0" indicates a high level of precision is required.
  2. Evaluate Glassware Precision: In a laboratory setting, different types of glassware have different levels of accuracy. Standard beakers and Erlenmeyer flasks are designed for mixing or holding liquids and provide only approximate volumes, while volumetric glassware is specifically calibrated for high-accuracy measurements.
  3. Understand the Function of a Volumetric Flask: A volumetric flask (Option A) is specifically designed "to contain" one specific volume of liquid at a specific temperature. It has a narrow neck with a single graduation mark (the "mark"), which allows for the most precise adjustment of the final volume of a solution.
  4. Consider the Solution Preparation Process: When preparing a solution from a solid, the solid is dissolved in a smaller amount of solvent first, and then solvent is added carefully until the bottom of the meniscus touches the graduation mark. This ensures that the total volume of the final mixture is exactly 500.0 mL.
  5. Conclusion: Because it is the only piece of glassware listed designed for high-precision containment of a fixed volume, the volumetric flask is the best choice.

WHY_OTHERS_WRONG:

  • B) Erlenmeyer flask & D) Graduated beaker: These are used for estimated measurements and mixing. Their markings typically have an error margin of 5% or more, making them unsuitable for preparing a solution where four significant figures (500.0 mL) are required.
  • C) Test tube: These are generally used for small-scale qualitative observations. They are not calibrated for precise volume measurements and are far too small to hold 500.0 mL of liquid.
  • E) Graduated cylinder: While more accurate than a beaker, a graduated cylinder is primarily designed "to deliver" varying volumes of liquid. For the highest level of precision in preparing a standard solution of a fixed volume, a volumetric flask is always preferred over a graduated cylinder.
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