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Step 1: NO(g) + O3(g) → NO2(g) + O2(g) Step 2: NO2(g) + O(g) → NO(g) + O2(g) A reaction mechanism foKinetics Chemistry Question

Question

Step 1: NO(g) + O3(g) → NO2(g) + O2(g)
Step 2: NO2(g) + O(g) → NO(g) + O2(g)

A reaction mechanism for the destruction of ozone, O3(g), is represented above. In the overall reaction, NO(g) is best described as

A.

an inhibitor

B.

a catalyst

✓ Correct
C.

a reactant

D.

an intermediate

E.

a product

💡 Solution & Explanation

STEPS:

1. Analyze the Elementary Steps: Look at the two-step mechanism provided in the sources:
* Step 1: NO(g)+O3(g)NO2(g)+O2(g)NO(g) + O_3(g) \rightarrow NO_2(g) + O_2(g)
* Step 2: NO2(g)+O(g)NO(g)+O2(g)NO_2(g) + O(g) \rightarrow NO(g) + O_2(g)
2. Track the Species NO(g): Observe the "life cycle" of nitric oxide (NONO) throughout the mechanism. It appears as a reactant in the very first step and is then regenerated as a product in the final step.
3. Determine the Overall Reaction: Sum the two elementary steps to see the net change. When adding them, species that appear on both the reactant and product sides cancel out:
* (NO+O3+NO2+O)(NO2+O2+NO+O2)(NO + O_3 + NO_2 + O) \rightarrow (NO_2 + O_2 + NO + O_2)
* After canceling NONO and NO2NO_2, the overall reaction is: O3(g)+O(g)2O2(g)O_3(g) + O(g) \rightarrow 2 O_2(g).
4. Apply the Definition of a Catalyst: In a reaction mechanism, a catalyst is a substance that is consumed in an early step but is regenerated in a subsequent step. Because it is present at the beginning and the end, it does not appear in the balanced overall equation but serves to provide a new pathway (mechanism) for the reaction.
5. Conclusion: Since NO(g)NO(g) is used in Step 1 and produced back in Step 2, it perfectly fits the definition of a catalyst.

WHY_OTHERS_WRONG:

  • A) inhibitor: An inhibitor is a substance that slows down or stops a reaction. The mechanism shown describes the *destruction* of ozone being facilitated by NONO, meaning it is speeding the process up, not inhibiting it.
  • C) reactant & E) product: While NONO appears as a reactant in one step and a product in another, it is neither in the overall reaction. A true reactant is consumed permanently, and a true product is newly formed at the end.
  • D) intermediate: This is a common point of confusion. An intermediate is a species that is produced in an early step and consumed in a later step (it is "born and then dies"). In this mechanism, NO2(g)NO_2(g) is the intermediate because it is created in Step 1 and used up in Step 2.
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