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Bond Polarity, VSEPR Theory, Intermolecular ForcesFRQ

The following information applies to parts A and B. 5. The Lewis diagram of CBrClF2 is shown.Bond Polarity, VSEPR Theory, Intermolecular Forces Chemistry Question

Problem Context

The following information applies to parts A and B.
5. The Lewis diagram of CBrClF2 is shown.

a.

Which of the bonds in CBrClF2 (C-Br, C-Cl, or C-F) is the most polar? Justify your answer.

b.

In a molecule of CBrClF2, the F-C-F bond angle is 106.8° and the Br-C-Cl bond angle is 112.3°. Explain the difference in bond angles using principles of atomic structure and VSEPR theory.

c(i).

Lewis diagrams and boiling points for CBr4 and CBrClF2 are given in the following table.

i. Clearly identify all the intermolecular forces in pure CBr4(l) and in pure CBrClF2(l).
CBr4(l):
CBrClF2(l):

c(ii).

ii. In terms of the relative strengths of all the intermolecular forces, explain why pure CBr4(l) has a higher boiling point than pure CBrClF2(l) does.

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