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Descriptive Chemistry / Organic ReactionsFRQ

[12%] Write net equations for each of the reactions below. Use appropriate ionic and molecular formuDescriptive Chemistry / Organic Reactions Chemistry Question

Problem Context

[12%] Write net equations for each of the reactions below. Use appropriate ionic and molecular formulas and omit formulas for all ions or molecules that do not take part in a reaction. Write structural formulas for all organic substances, and clearly show stereochemistry where relevant. You need not balance the equations or show the phases of the species.

a.

Sulfur dioxide is bubbled through barium hydroxide solution.

Model Answer

Ba2+(aq) + SO2(g) + OH–(aq) → BaSO3(s) + H2O(l)

b.

Phosphorus pentachloride is heated with phosphorus(V) oxide.

Model Answer

PCl5(s) + P4O10(s) → POCl3(l)

c.

Cobalt(II) nitrate is dissolved in concentrated aqueous hydrochloric acid.

Model Answer

Co(NO3)2(s) + Cl–(aq) → CoCl4 2–(aq) + NO3–(aq)

d.

Iron(II) ammonium sulfate reacts with potassium dichromate in dilute sulfuric acid.

Model Answer

Cr2O7 2–(aq) + Fe2+(aq) + H+(aq) → Cr3+(aq) + Fe3+(aq) + H2O(l)

e.

Bromine is added to 4-nitrotoluene in the presence of anhydrous iron(III) bromide.

f.

Acetone (2-propanone) is added to an aqueous solution of hydroxylamine.

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