Account for the following statements or observations in terms of atomic-, ionic- or molecular-level — Atomic Structure and Periodicity / Chemical Bonding Chemistry Question
Problem Context
Account for the following statements or observations in terms of atomic-, ionic- or molecular-level explanations.
Magnesium exists as +2 ions rather than +1 ions in all of its compounds despite the fact that the second ionization energy of a magnesium atom is more than twice as great as the first ionization energy.
Model Answer
The Mg2+ ion is smaller and has a higher charge than the Mg+ ion, so the lattice energy that arises when Mg2+ ions form compounds is much greater than what would be observed if Mg+ ions formed compounds. The increase in lattice energy more than offsets the larger ionization energy of the Mg2+ ion.
Titanium forms ions with different charges (+2, +3 and +4). The first two of these ions are colored while the last is colorless.
Model Answer
Ti (atomic number 24) has a valence electron configuration of 4s23d2 and can form +2 ions by losing it’s two 4s electrons, +3 ions by losing the two 4s electrons and one 3d electron and +4 by losing all four of the valence electrons. The +2 and +3 ions are colored because of electronic transitions between d orbitals. The +4 ion does not exhibit color because it has no valence d-electrons to undergo electronic transitions.
Carbon dioxide (CO2) is a gas at room temperature but silicon dioxide (SiO2) is a high melting solid.
Model Answer
Carbon dioxide (O=C=O) molecules are nonpolar and interact with each other only through weak dispersion forces. These weak forces are easily overcome so CO2 is a gas at room temperature. SiO2 doesn’t have the same molecular formula, because Si does not form double bonds as readily as carbon does. Si-O form single bonds that lead to a network solid held together with strong, covalent bonds, so it is a solid that has a high melting point.
Nitrogen forms NF3 but not NF5 whereas phosphorus forms PF3 and PF5. The trifluorides are both trigonal pyramidal and the pentafluoride is trigonal bipyramidal.
Model Answer
Nitrogen can form three bonds (NF3) but not five (NF5) because it lacks d orbitals that are energetically available for the formation of hybrid orbitals (or alternatively, because it is too small to accommodate five atoms.) Both NF3 and PF3 are trigonal pyramidal because the central atom has three bonding pairs and one lone pair of electrons (leading to sp3 hybridization). PF5 is trigonal bipyramidal because it has five bonding pairs (leading to dsp3 hybridization.)