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Simple chemical tests are often utilized for qualitative analyses of inorganic and organic compounds โ€” Organic Chemistry Chemistry Question

Identification of polymers and small organic molecules by qualitative analysis

Simple chemical tests are often utilized for qualitative analyses of inorganic and organic compounds. Identification of unknown compounds requires a wide range of chemical knowledge. In order to identify inorganic compounds, unknown compounds are classified on the basis of their behavior to reagents which bring about acid-base, and/or redox reactions, sometimes producing precipitations. For organic compounds, the chemical reactions of functional groups present in the molecule are used for identification purposes. For polymeric compounds, the additional effects characteristic of macromolecules should be taken into consideration in order to identify the compounds. Suppose that a polymer solution with a functional group A in each repeating unit is mixed with a solution of a chemically complementary polymer with a functional group B, and that there are attractive interactions between A and B. Due to the presence of a large number of the repeating units, the intermolecular attractive interactions inherent in polymers are stronger than those of the corresponding small molecules. Combining such polymers forms a polymer-polymer complex. The complex usually shows lower solubility than the individual polymers, and precipitation of the complex is often observed. In this experiment, you will have five unknown aqueous solutions (A โ€“ E), each containing one of the compounds below (all of which are used). Carry out the following experiments and answer the questions.

poly(methacrylic acid) ethylene glycol
poly(sodium 4-styrenesulfonate) aniline hydrochloride
succinic acid

[VISUAL]

38.1.

Identify the compound in each solution from the results of procedures 1 and 2 above.

38.2.

Give the equations for the reaction of aniline hydrochloride with anhydrous sodium carbonate and for the reaction of succinic acid with anhydrous sodium carbonate.

38.3.

Is it possible to identify the compound by utilizing poly(ethyleneimine hydrochloride) instead of poly(allylamine hydrochloride)? Explain.

Model Answer

Yes. Poly(ethylene imine hydrochloride) (PEI) behaves as a polycation in an aqueous solution, where a polymer chain is positively charged like poly(allyamine hydrochloride). When the PEI solution is mixed with a solution of a polyanion such as poly(sodium 4-styrenesulfonate), a polymer โ€“ polymer complex is formed, and a precipitation is observed.

38.4.

Report on the changes in appearance of the mixed solution in part 3 of the procedures and interpret these results.

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