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Physical Chemistry — KineticsIChO

You have moderately concentrated (5 - 6 % by mass) aqueous solutions containing water-soluble compouPhysical Chemistry — Kinetics Chemistry Question

PREPARATORY PRACTICAL PROBLEM P3

You have moderately concentrated (5 - 6 % by mass) aqueous solutions containing water-soluble compounds of the following cations with one of the most common anions (chloride, sulfate or nitrate):
NH4+, Li+, Na+, Mg2+, Al3+, K+, Ca2+, Cr3+, Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Sr2+, Ag+, Sn2+, Sn4+, Sb3+, Ba2+, Pb2+, Bi3+.

P4.1.

Observe the color and the pH of the solutions.

P4.2.

Study the reactions of these cations with the anions used in systematic qualitative analysis: chloride, sulfide, carbonate, and hydroxide. Note that some sulfides can be precipitated even from acidic solutions, others are soluble in dilute strong acids, some are soluble in water, and some would react with water. Most cations will give a precipitate with CO3 2-. What happens if you use HCO3– instead?
Whenever you observe no reaction at ambient temperature, try to predict whether boiling the solution would bring about a detectable change.

P4.3.

Learn which cations react with some common anions: nitrate, nitrite, phosphate, sulfate, perchlorate, bromide, and iodide. Throughout this problem, use solutions in the same concentration range (approximately 5-6 % by mass).

P4.4.

Which two cations in the list above cannot be distinguished from each other on the basis of their reactions with the anions mentioned so far?

P4.5.

Using the reactions you have learned, identify five unknown aqueous solutions. Every solution was made from a single compound which may contain any of the cations and anions you have encountered in this problem.

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