Mixing which 0.1 M aqueous solutions results in formation of a colored precipitate? | Descriptive Chemistry

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Mixing which 0.1 M aqueous solutions results in formation of a colored precipitate?

BaCl₂ and CH₃COOH

BaCl₂ and Na₂CO₃

CuCl₂ and CH₃COOH

CuCl₂ and Na₂CO₃

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