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States of MatterMCQ

A pure sample of benzene (C6H6) melts sharply at 5.5 °C, while a pure sample of hexafluorobenzene (CStates of Matter Chemistry Question

Question

A pure sample of benzene (C6H6) melts sharply at 5.5 °C, while a pure sample of hexafluorobenzene (C6F6) melts sharply at 5.2 °C. However, an equimolar mixture of C6H6 and C6F6 melts sharply at 23.7 °C. Which is the best explanation for this observation?

A.

C6H6 and C6F6 are immiscible in the liquid phase.

B.

C6H6 and C6F6 form a crystal containing equal amounts of the two substances.

✓ Correct
C.

Fluorocarbons characteristically show negative freezing point depression constants.

D.

The enthalpy of mixing of C6H6 and C6F6 is negative.

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