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In the gas phase PCl5 exists as individual molecules but in the solid it takes on the ionic structurBonding Chemistry Question

Question

In the gas phase PCl5 exists as individual molecules but in the solid it takes on the ionic structure PCl4+PCl6–. What are the geometries of these three species

A.

PCl5: trigonal bipyramidal, PCl4+: see-saw, PCl6–: octahedral

B.

PCl5: trigonal bipyramidal, PCl4+: tetrahedral, PCl6–: octahedral

✓ Correct
C.

PCl5: trigonal bipyramidal, PCl4+: square planar, PCl6–: distorted octahedral

D.

PCl5: square pyramidal, PCl4+: see-saw, PCl6–: square planar

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