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Triiodide reacts with acetone in acidic aqueous solution: I3–(aq) + CH3COCH3(aq)  CH3COCH2I(aq) + 2Kinetics Chemistry Question

Question

Triiodide reacts with acetone in acidic aqueous solution:
I3–(aq) + CH3COCH3(aq)  CH3COCH2I(aq) + 2 I–(aq) + H+(aq)
The reaction is carried out twice, both times with [I3–]0 = 1.0  10–3 M and [H+]0 = 1.00 M, but with two different concentrations of acetone, and the concentration of triiodide is found to vary with time as shown:

What are the orders of triiodide and acetone in the reaction?

A.

First-order in I3–, first-order in CH3COCH3

B.

Zeroth-order in I3–, first-order in CH3COCH3

✓ Correct
C.

First-order in I3–; the order in CH3COCH3 cannot be determined from the available data

D.

First-order in CH3COCH3; the order in I3– cannot be determined from the available data

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